{"created":"2023-05-15T16:14:26.930665+00:00","id":45007,"links":{},"metadata":{"_buckets":{"deposit":"986f285c-d87f-48de-842e-103e1c350af4"},"_deposit":{"created_by":25,"id":"45007","owners":[25],"pid":{"revision_id":0,"type":"depid","value":"45007"},"status":"published"},"_oai":{"id":"oai:shinshu.repo.nii.ac.jp:00045007","sets":["2668"]},"author_link":["174369","174368","174371","174370"],"item_20002_biblio_info_27":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-04-18","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"734","bibliographicPageStart":"727","bibliographicVolumeNumber":"47","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF APPLIED ELECTROCHEMISTRY"}]}]},"item_20002_creator_3":{"attribute_name":"作成者(その他言語)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Munkhbat, Mendsaikhan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arai, Susumu"}],"nameIdentifiers":[{}]}]},"item_20002_date_19":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2020-01-30","subitem_date_issued_type":"Created"}]},"item_20002_description_14":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Toward the realization of reliable Li-ion batteries with high performance and safety, component materials such as those of the current collector and negative electrode require further innovation. Sn, one of the most promising negative-electrode materials, can be electrochemically fixed on a substrate without any binder or conductive additive. However, the pulverization of Sn-plated films on substrates caused by large volume changes during Li-Sn reactions is the main reason hindering the practical application of Sn-plated electrodes. In the present study, we developed an electrodeposited three-dimensional (3D) Cu substrate applied to underlayer of the electrode. The effect of substrate geometry on the charge-discharge performance of the Sn electrode was investigated. The 3D-Cu/Sn electrode exhibited superior cycling performance with a reversible capacity of 470 mA h g(-1) even at the 300th cycle, whereas the Sn-plated electrode prepared on a typical flat Cu substrate showed a capacity of only 20 mA h g(-1). The results demonstrated that the 3D structure played a key role in accommodating volumetric changes in the Sn to suppress electrode disintegration. The developed 3D-Cu substrate will be significantly useful as a current collector for alloy-based active materials. [GRAPHICS] .","subitem_description_type":"Other"}]},"item_20002_description_20":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_20002_description_22":{"attribute_name":"その他の資源識別子","attribute_value_mlt":[{"subitem_description":"JOURNAL OF APPLIED ELECTROCHEMISTRY.47(6):727-734(2017)","subitem_description_type":"Other"}]},"item_20002_full_name_16":{"attribute_name":"公開者(その他言語)","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"SPRINGER"}]}]},"item_20002_identifier_23":{"attribute_name":"資源識別子URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/10091/00021825"}]},"item_20002_relation_32":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1007/s10800-017-1075-0","subitem_relation_type_select":"DOI"}}]},"item_20002_rights_50":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is a post-peer-review, pre-copyedit version of an article published in JOURNAL OF APPLIED ELECTROCHEMISTRY. The final authenticated version is available online at: http://dx.doi.org/10.1007/s10800-017-1075-0"},{"subitem_rights":"This is a post-peer-review, pre-copyedit version of an article published in JOURNAL OF APPLIED ELECTROCHEMISTRY. The final authenticated version is available online at: http://dx.doi.org/10.1007/s10800-017-1075-0"}]},"item_20002_source_id_25":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-891x","subitem_source_identifier_type":"ISSN"}]},"item_20002_source_id_26":{"attribute_name":"処理レコードID(総合目録DB)","attribute_value_mlt":[{"subitem_source_identifier":"AA11981601","subitem_source_identifier_type":"NCID"}]},"item_20002_version_type_51":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"url":{"url":"https://soar-ir.repo.nii.ac.jp/?action=repository_action_common_download&item_id=21068&item_no=1&attribute_id=65&file_no=1"}},{"url":{"url":"https://soar-ir.repo.nii.ac.jp/?action=repository_action_common_download&item_id=21068&item_no=1&attribute_id=65&file_no=2"}}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Electrodeposition","subitem_subject_scheme":"Other"},{"subitem_subject":"Sn electrode","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery","subitem_subject_scheme":"Other"},{"subitem_subject":"Three-dimensional structure","subitem_subject_scheme":"Other"},{"subitem_subject":"Current collector","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method"}]},"item_type_id":"20002","owner":"25","path":["2668"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-09-04"},"publish_date":"2020-09-04","publish_status":"0","recid":"45007","relation_version_is_last":true,"title":["Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method"],"weko_creator_id":"25","weko_shared_id":-1},"updated":"2023-05-15T18:09:40.213962+00:00"}