{"created":"2023-05-15T16:12:05.559967+00:00","id":42505,"links":{},"metadata":{"_buckets":{"deposit":"3e490980-ac60-4506-89df-4b9d3d1c16f3"},"_deposit":{"created_by":25,"id":"42505","owners":[25],"pid":{"revision_id":0,"type":"depid","value":"42505"},"status":"published"},"_oai":{"id":"oai:shinshu.repo.nii.ac.jp:00042505","sets":["2668"]},"author_link":["166140","166139","166138","166137"],"item_20002_biblio_info_27":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-05-21","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19","bibliographicPageEnd":"3607","bibliographicPageStart":"3601","bibliographicVolumeNumber":"6","bibliographic_titles":[{"bibliographic_title":"Polymer Chemistry"}]}]},"item_20002_creator_3":{"attribute_name":"作成者(その他言語)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kohsaka, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamamoto, Kazuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kitayama, Tatsuki"}],"nameIdentifiers":[{}]}]},"item_20002_date_19":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2018-01-22","subitem_date_issued_type":"Created"}]},"item_20002_description_14":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Isotactic and syndiotactic poly(methyl methacrylate)s with orthogonally double-clickable terminal ends, that is, α,β-unsaturated esters for Michael addition-type thiol–ene reactions and azide or alkynyl groups for azide–alkyne click reactions, were prepared via a terminating reaction of stereospecific anionic polymerization with propargyl and 2-chloroethyl α-(chloromethyl)acrylates. The subsequent polymer modification via a double click reaction proceeded quantitatively in a one-pot system under ambient conditions. The facile and almost quantitative double-end-functionalization would open a new material design based on stereoregular PMMAs with controlled molecular weights.","subitem_description_type":"Other"}]},"item_20002_description_20":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_20002_description_22":{"attribute_name":"その他の資源識別子","attribute_value_mlt":[{"subitem_description":"Polymer Chemistry.6(19):3601-3607(2015)","subitem_description_type":"Other"}]},"item_20002_full_name_16":{"attribute_name":"公開者(その他言語)","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"The, Royal Society of Chemistry"}]}]},"item_20002_identifier_23":{"attribute_name":"資源識別子URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/10091/00020192"}]},"item_20002_relation_32":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/C5PY00357A","subitem_relation_type_select":"DOI"}}]},"item_20002_rights_50":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Polymer Chemistry.6(19):3601-3607(2015)- Reproduced by permission of The Royal Society of Chemistry. There shall be a link from this article to the PDF of the final published article on the RSC's website once this final version is available."},{"subitem_rights":"Polymer Chemistry.6(19):3601-3607(2015) - Reproduced by permission of The Royal Society of Chemistry. There shall be a link from this article to the PDF of the final published article on the RSC's website once this final version is available."}]},"item_20002_source_id_25":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1759-9954","subitem_source_identifier_type":"ISSN"}]},"item_20002_version_type_51":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"url":{"url":"https://soar-ir.repo.nii.ac.jp/?action=repository_action_common_download&item_id=19431&item_no=1&attribute_id=65&file_no=1"}}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction"}]},"item_type_id":"20002","owner":"25","path":["2668"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-09-04"},"publish_date":"2020-09-04","publish_status":"0","recid":"42505","relation_version_is_last":true,"title":["Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction"],"weko_creator_id":"25","weko_shared_id":-1},"updated":"2023-05-15T18:32:33.843926+00:00"}