@article{oai:shinshu.repo.nii.ac.jp:00042505, author = {Kohsaka, Yasuhiro and Yamamoto, Kazuki and Kitayama, Tatsuki}, issue = {19}, journal = {Polymer Chemistry}, month = {May}, note = {Isotactic and syndiotactic poly(methyl methacrylate)s with orthogonally double-clickable terminal ends, that is, α,β-unsaturated esters for Michael addition-type thiol–ene reactions and azide or alkynyl groups for azide–alkyne click reactions, were prepared via a terminating reaction of stereospecific anionic polymerization with propargyl and 2-chloroethyl α-(chloromethyl)acrylates. The subsequent polymer modification via a double click reaction proceeded quantitatively in a one-pot system under ambient conditions. The facile and almost quantitative double-end-functionalization would open a new material design based on stereoregular PMMAs with controlled molecular weights., Article, Polymer Chemistry.6(19):3601-3607(2015)}, pages = {3601--3607}, title = {Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction}, volume = {6}, year = {2015} }